2-Methylbenzaldehyde

2-Methylbenzaldehyde
Names
	Preferred IUPAC name 2-Methylbenzaldehyde
	Other names o-Tolualdehyde
Identifiers
CAS Number	529-20-4;
3D model (JSmol)	Interactive image;
3DMet	B01081;
Beilstein Reference	605841
ChEBI	CHEBI:27434;
ChEMBL	ChEMBL1487138;
ChemSpider	21106524;
ECHA InfoCard	100.007.685
EC Number	208-452-2;
Gmelin Reference	3304
KEGG	C07214;
PubChem CID	10722;
UNII	Q7E5H6W6BG;
CompTox Dashboard (EPA)	DTXSID1022051 ;
	InChI InChI=1S/C8H8O/c1-7-4-2-3-5-8(7)6-9/h2-6H,1H3 Key: BTFQKIATRPGRBS-UHFFFAOYSA-N;
	SMILES CC1=CC=CC=C1C=O;
Properties
Chemical formula	C8H8O
Molar mass	120.151 g·mol−1
Appearance	colorless liquid
Density	1.0328 g/cm3 (20 °C)
Melting point	−35 °C (−31 °F; 238 K)
Boiling point	199–200 °C (390–392 °F; 472–473 K)
Hazards
	GHS labelling:
Pictograms
Signal word	Danger
Hazard statements	H302, H314, H315, H319, H335
Precautionary statements	P260, P261, P264, P270, P271, P280, P301+P312, P301+P330+P331, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P310, P312, P321, P330, P332+P313, P337+P313, P362, P363, P403+P233, P405, P501
Flash point	67 °C; 153 °F; 340 K
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

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2-Methylbenzaldehyde is an organic compound with the formula CH₃C₆H₄CHO. It is a colorless liquid.^[1]

Use and occurrence

Of its many reactions, 2-methylbenzaldehyde undergoes BF₃-induced Rothemund condensation with pyrrole to give atropoisomers of tetrakis(o-tolyl)porphyrin.^[2]

It is one of main benzaldehyde component of automobile exhaust.^[3]

Related compounds

References

^ H. B. Hass; Myron L. Bender (1950). "o-Tolualdehyde". Org. Synth. 30: 99. doi:10.15227/orgsyn.030.0099.
^ Lindsey, Jonathan S.; Wagner, Richard W. (1989). "Investigation of the synthesis of ortho-substituted tetraphenylporphyrins". J. Org. Chem. 54 (4): 828–36. doi:10.1021/jo00265a021.
^ Rogge, Wolfgang F.; Hildemann, Lynn M.; Mazurek, Monica A.; Cass, Glen R.; Simoneit, Bernd R. T. (1993). "Sources of fine organic aerosol. 2. Noncatalyst and catalyst-equipped automobiles and heavy-duty diesel trucks". Environmental Science and Technology. 27 (4): 636–51. Bibcode:1993EnST...27..636R. doi:10.1021/es00041a007.

[1] H. B. Hass; Myron L. Bender (1950). "o-Tolualdehyde". Org. Synth. 30: 99. doi:10.15227/orgsyn.030.0099.

[2] Lindsey, Jonathan S.; Wagner, Richard W. (1989). "Investigation of the synthesis of ortho-substituted tetraphenylporphyrins". J. Org. Chem. 54 (4): 828–36. doi:10.1021/jo00265a021.

[3] Rogge, Wolfgang F.; Hildemann, Lynn M.; Mazurek, Monica A.; Cass, Glen R.; Simoneit, Bernd R. T. (1993). "Sources of fine organic aerosol. 2. Noncatalyst and catalyst-equipped automobiles and heavy-duty diesel trucks". Environmental Science and Technology. 27 (4): 636–51. Bibcode:1993EnST...27..636R. doi:10.1021/es00041a007.

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